Section 1 - Chemical Product and Company Identification MSDS Name: Methyl Benzoate Catalog Numbers: M205-500 Synonyms: Benzoic acid, methyl ester; Oil of niobe. This supplier was in ECHEMIs Top 10 Suppliers list last year. Marketing authorisation number(s) 9. May be harmful if It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees. 6, flavors, propylene glycol, sodium benzoate, sodium chloride, sorbitol, sugar, and water. Precautions for Scalp and Hair Treatment: Avoid contact with the eyes. 0000011858 00000 n Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . May be harmful if inhaled. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. Preparation of methyl 3-nitrobenzoate. d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. Uses advised against Food, drug, pesticide or biocidal product use. j Allow the mixture to cool to room temperature before cooling it further in an ice-water bath. dynamic viscosity (in mPa s) = 1.94. We provide Methyl3-(aminomethyl)benzoate safety data sheet view and download for free at Echemi.com. Methyl Benzoate has been found in essential oils (e.g., ylang-ylang oil). If patient is extubated between days 1 to 14, advance to day 15 : 93-89-0 1.2 Relevant identifie d uses of the substance or mixture and uses advised against 6.1 Personal It works by changing the internal pH of microorganisms to an acidic state that is incompatible with their growth and survival. Fight fire with normal precautions from a reasonable distance. ; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. Nitration is the substitution of an NO2 group for one of the hydrogen atoms on a benzene ring. Perform CPR as necessary. National Ocean Service, 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. However the 3-position is less deactivated towards nitration than the other positions owing to the relative stability of the different intermediates. Synthetic Anti-infective Drugs Nervous System Drugs Fluid, Electrolyte, and Acid-base Balance Vitamins and Minerals Medicines Digestive System Drugs Blood System Drugs Circulatory System Drugs Diagnostic Agents Specialty Drugs Drug Metabolism Feed Additive Anti-stress Drugs Drugs Influencing Immune Function Veterinary Raw Materials Inhibitor Drugs It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. 0000005585 00000 n 20 g) of crushed ice held in a beaker. Diazepam rectal gel contains 5 mg/mL diazepam, propylene glycol, ethyl alcohol (10%), hydroxypropyl methylcellulose, sodium benzoate, benzyl alcohol (1.5%), benzoic acid and water. Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in a prefilled, unitdose, rectal delivery system. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. Set up emergency exits and the risk-elimination area. Drug Interaction Studies and PRECAUTIONS.) Temperature:23.0C. It is an ester with the chemical formula C6H5CO2CH3. Blister formation, crusting, itching, oozing, reddening, or scaling of skin. If it pass ECHEMI audit , supplier can get logo of certified business license. 0000008079 00000 n Contains Methyl (E218) and Propyl (E216) parahydroxybenzoates which may cause allergic reactions (possibly delayed). 5VB_". 6.1 Personal precautions . What Is Wrong With Disney Adults. SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. Solid methyl 3-nitrobenzoate will form. It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. When heated to decomposition it emits Methyl 3-nitrobenzoate is insoluble in water but soluble in hot ethanol. 3 0 obj METHYL BENZOATE is an ester. EYES: First check the victim for contact lenses and remove if present. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. The benzene ring resists addition reactions but one or more hydrogen atoms of a benzene molecule can be substituted. Therefore the reaction is regioselective for nitration at the 3-position. Future Technologies L.L.C Remove all sources of ignition. SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. v!nhUicZ^H,YE$}(jv2. Combustible. May cause respiratory tract irritation. Diazomethane is the chemical compound CH 2 N 2, discovered by German chemist Hans von Pechmann in 1894. stream P381: Eliminate all ignition sources if safe to do so. See Notes. Hazard Statements. 0000000016 00000 n : 5026-62- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. 0000005469 00000 n with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Central Drug House (P . Benzoic acids salt (sodium benzoate) is commonly used as a pH adjustor and preservative in food, preventing the growth of microbes to keep food safe. Tested undiluted, Methyl Benzoate, Ethyl Benzoate, Butyl Benzoate and Isopropyl Benzoate were considered mild eye and skin irritants. It also finds use as a solvent and as a pesticide used to attract The principal food safety incident in Taiwan was over the use of the plasticizer DEHP to replace palm oil in food and drinks as a clouding agent. Appearance: clear to light yellow liquid. Office of Response and Restoration, Do not let product enter drains. METYL TERT-BUTYL ETHER. Ethyl hydroxybenzoate (E214) 5mg/5ml. %PDF-1.6 % Handling in a well ventilated place. Denser than water. 26 0 obj <> endobj Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Esters react with acids to liberate heat along with alcohols and acids. The safety of Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate has been assessed by the Cosmetic Ingredient Review (CIR) Expert Panel. The adsorption of methyl benzoate was determined by a modified version of the OECD guideline 106, a batch equilibrium method, in three soils with different characteristics: an acid forest soil (Podzol), an agricultural soil (Alfisol), and a sediment. miscible with ether, soluble in methanol and ether, insoluble in water and glycerol. 0000004074 00000 n These side effects may go away during treatment as your body adjusts to the medicine. 0000000976 00000 n This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. (2) Just because you expect a particular result doesn't mean that's what will happen. The oralLD50 values in mice and rats are 3330 and1350 mg/kg, respectively. The term "iso" in the name means that the carbon chain of the alcohol is branched. endstream endobj 27 0 obj > endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned. endobj Approved respirator, chemical safety goggles, chemical-resistant gloves. 0000004601 00000 n Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Methyl benzoate is an organic compound. Based on the information reviewed, the CIR Expert Panel concluded that Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate were safe as used in cosmetic products. Do not induce vomiting. P.O box : 92 , Postal Code : 102 Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. (USCG, 1999), Immediate first aid: Ensure that adequate decontamination has been carried out. stream Precautions for safe handling : Avoid contact with skin, eyes and clothing. Revision Date: January 20, 2015. for cellulose esters and ethers, resins and rubber. Esters react with acids to liberate heat along with alcohols and acids. It reacts both at the ring and the ester. Manager Quality Control Mindaugas Marksa Kaunas, Lithuania Date 26.07.2021 . P301+P317 IF SWALLOWED: Get medical help. - No smoking. The recrystallization is carried out from a mixture of water and ethanol. Marketing authorisation holder; 8. 0000004296 00000 n GHS07. P390: Absorb spillage to prevent material damage. : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Causes redness and pain. (NTP, 1992). fire. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! Rinse and then wash skin with water and soap. Methyl benzoate CAS-No. This section provides a listing of alternate names for this chemical, The concentration of the ester enolate anion of methyl propanoate in the mixture is much smaller than that of methyl benzoate. Cocaine hydrochloride hydrolyzes in moist air to give methyl benzoate; drug - sniffing dogs are thus trained to detect the smell of methyl benzoate. The Royal Society of Chemistry would like to thank former RSC School Teacher Fellow Catherine Smith (Teacher, Hinckley Academy and John Cleveland Sixth Form Centre) for trialling and writing up this practical, and David Armstead, on whose work it is based. IDA (FLAMMABLE highly flammable liquid and vapour; MODERATE HAZARD harmful if swallowed, may cause damage to organs) can be used instead. product with regard to appropriate safety precautions. SAFETY DATA SHEET Version 5.2 Revision Date 04/02/2015 Print Date 12/20/2016 1. Diflucan (fluconazole), the first of a new subclass of synthetic triazole antifungal agents, is available as tablets for oral administration, as a powder for oral suspension.. Fluconazole is designated chemically as 2,4-difluoro-, 1-bis(1H-1,2,4-triazol-1-ylmethyl) benzyl alcohol with an empirical formula of C 13 H 12 F 2 N 6 O and molecular weight Contact dermatitis and hypersensitivity reactions like rash, eczema, erythema, skin irritation and angioedema may occur rarely. This medicine contains 6.3 mg of sodium benzoate in each 5 ml, which is equivalent to 1.26 mg/ml. SAFETY DATA SHEET Version 6.6 Revision Date 09/16/2021 Print Date 01/15/2023 . Ensure thorough mixing. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Hazards and Precautions. Incompatible with strong oxidizing agents, strong acids, strong bases. 0000002359 00000 n 0000017521 00000 n SODIUM BENZOATE 0.2% Sodium Benzoate. Methyl benzoate is an organic compound. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New . xSn0h VHzu^Z5S:i8F k H: b7&Rls3C!5p'ToVzYc][k-R^BDA%bQ-qx9e7?kyLn#8 7}+N'?tR2%::`1-- wmeQ=VpmWuSAt+3 %PDF-1.4 IDENTIFICATION Product Description: METHYL BENZOATE FCC CAS # 93-58-3 . Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. : 93-58-3 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against . Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. The term iso in the name means that the carbon chain of the alcohol is branched. Esters react with acids to liberate heat along with alcohols and acids. Methyl benzoate The chemical name is (S)-6-methoxy--methyl-2-naphthalene acetic acid. b Slowly add 4 cm3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. %PDF-1.4 Stable under recommended storage conditions. ingestion. The molecular weight is 230.26 Its molecular formula is C 14 H 14 O 3 , and it has the following chemical structure. ethanol (FLAMMABLE highly flammable liquid and vapour). Methyl benzoate is an organic compound. ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. <> May cause skin irritation. MSDS Name: Methyl Benzoate May be slightly toxic by ingestion. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product. Handle in accordance with good industrial hygiene and safety practice. The respective Freundlich constants, Kf (1/n), for the three soils were 8.64 (0.81), 1.29 (0.85), and 1.51 (0.84)(1). <> foam, CO2, dry chemical, water to blanket Thermacell Radius Zone Mosquito Repellent, if absorbed through the skin. Do not discharge to sewer systems. Methyl benzoate can be converted simply into other benzoates by transesterification. Cool this mixture by partially immersing the flask in an ice-water bath. SAFETY DATA SHEET. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Combustible liquid and vapor. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Special Hazards of Combustion Products: None (USCG, 1999). Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. Collect leaking and spilled liquid in sealable containers as far as possible. Chronic: It also finds use as a solvent. Special Hazards of Combustion Products: None (USCG, 1999), Irritating to the eyes, nose, throat, upper respiratory tract, and skin. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. P390: Absorb spillage to prevent material damage. 4; H302 <= 100 % EC-No. Methyl benzoate | C6H5COOCH3 - PubChem Apologies, we are having some trouble retrieving data from our servers. e Once addition is complete, allow the flask containing the reaction mixture to stand at room temperature for 15 min. Some side effects may occur that usually do not need medical attention. Vapors can accumulate in low areas. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. It has a role as a metabolite and an insect attractant. 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 01 Revision Date: 02-02-2015 Print Date: 11-26-2015 Page 1 of 10 1. 0000006427 00000 n nitration using concentrated sulfuric acid and concentrated nitric acid, Structure and bonding: exploding exam questions | 1416 years, Lithium-ion cells worksheet | 1618 years, Spot the entropy errors worksheet | 1618 years. 0000003831 00000 n These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. Normally stable, even under fire conditions. It is the simplest diazo compound.In the pure form at room temperature, it is an extremely sensitive explosive yellow gas; thus, it is almost universally used as a solution in diethyl ether.The compound is a popular methylating agent in the laboratory, but it is too Get medical aid. Dyzana Paintball Pants, Clorius; Essence of niobe; Benzoic acid,methyl ester. After completion stir for 5 more min. Naproxen, USP is a white to off-white crystalline powder. GSM: +968 9800 4222 Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). (NTP, 1992). Methyl hydroxybenzoate (E218)1mg/5ml. Electron-withdrawing groups have a deactivating effect on the ring. Precautionary Statements. Moderately toxic by <> 0000002518 00000 n If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. VIP Supplier is a premium membership for suppliers on ECHEMI.COM. Members are provided with comprehensive ways to promote their products. It does not represent any guarantee of the properties of the product. 1. It is a colorless liquid with a strong, dry-fruity, slightly phenolic odor. 0000017078 00000 n (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. P376: Stop leak if safe to do so. Identification Product Name Methyl benzoate Cat No. Fish and shellfish concentrate mercury in their bodies, often in the form of methylmercury, a highly toxic organomercury compound. http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr, http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, http://ec.europa.eu/consumers/cosmetics/cosing/. with oxidizing materials. Ingestion: Never give anything by mouth to an unconscious person. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. (n.). Do you expect ortho-, meta-, or para-nitration? SODIUM BORATE, DECAHYDRATE By Molarity 0.1 M Sodium Borate Environmental Health and Safety 416.978.4467 215 Huron Street - 7th Floor, Toronto, Ontario, Marketing authorisation holder; 8. Methyl benzoate is formed by the condensation of methanol and benzoic acid, in presence of a strong acid such as hydrochloric acid . (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. g Allow the ice to melt and filter under suction. Synthesise and recrystallize a sample of methyl 3-nitrobenzoate. endobj Methyl Benzoate and Ethyl Benzoate and other related compounds did not cause mutations. receptor type. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. Koc values for the Podzol, Alfisol and sediment were 178, 103, and 95, respectively(1). [6] 1 Anasazi Experiment Series. SAFETY ASSESSMENT, PRODUCT INFORMATION FILE, NOTIFICATION. AEROBIC: Methyl benzoate, present at 28 mg/L in activated sewage sludge, achieved 62% biodegradation in 29 days using a Modified Sturm test measuring carbon dioxide evolution and is considered readily biodegradable(1). Stable. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. Tel: +968-2250 7015 All rights reserved, METHYL BENZOATE / BENZOIC ACID METHYL ESTER, Analytical Chromatography Product Catalog, 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethoxy)-, Methyl 3-[isocyano(toluene-4-sulphonyl)methyl]benzoate, Ethyl 3-bromo-4-[(4-methylpiperazin-1-yl)methyl]benzoate, [(1S,2S,6R)-5,6-diacetyloxy-1-hydroxy-2-(2-hydroxyethoxy)-1-cyclohex-3 -enyl]methyl benzoate, 1-(N-methyl-N-nitrosamino)methyl benzoate, methyl 4-((6-fluoro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((2,3-dihydro-6-nitro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((6-chloro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, 3-AMINO-5-TERT-BUTYLBENZOIC ACID METHYL ESTER3-AMINO-5-TERT-BUTYL-METHYL BENZOATE, Methyl 4-[(Z)-amino(hydroxyimino)methyl]benzoate 95%, Methyl 3-{[4-(trifluoromethyl)piperidin-1-yl]methyl}benzoate, Methyl 3-[(4-methylpiperazin-1-yl)methyl]benzoate 97%, Disodium 5-[(E)-(3-carboxylato-5-methyl-4-oxo-1-cyclohexa-2,5-dienylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methyl-benzoate. appropriate safety precautions. May cause eye irritation. 5.3 Preclinical safety data; 6. . Wash the ester with dilute aqueous NaHCO3, then water, dry with Na2SO4 and fractionally distil it in a vacuum. Heat is also generated by the interaction of esters with caustic solutions. azure data factory if dynamic content. The nitrating mixture must be made in situ as required and kept cool throughout. DOSAGE AND ADMINISTRATION. % No information found. 1 0 obj CHEMICAL Do you expect ortho-, meta-, or para-nitration? It does not represent any guarantee of the properties of the product. H302. : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . Causes redness and pain. Download COA. (For reference only, please check.). sudden loss of consciousness. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. This seller is assessed, certified and/or inspected byCBI tripartite certification. 1 Reagent Lane Sigma-Aldrich Corporation and its Affiliates shall not be . IDENTIFICATION Product Description: METHYL BENZOATE FCC Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. 4 0 obj 0000009293 00000 n 0000001433 00000 n observed. 1 0 obj Take precautionary Warning. METHYL BENZOATE is an ester. Cool the nitric acid by partially immersing it in an ice-water bath before slowly adding, with swirling, 1.5 cm3 of concentrated sulfuric acid. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). Safety Information. Avoid breathing vapors, mist or gas. Keep in suitable, closed containers for disposal. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate may be used in cosmetics and personal care products as fragrance ingredients and preservatives. <> (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. Recommended Use Laboratory chemicals. Wash the crude product with a little ice-cold water. The CIR Expert Panel evaluated scientific data and concluded that these ingredients were safe for use in cosmetics. According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. : 93-58-3 1.2 Relevant identified uses of the substance or mixture and uses advised against . It may also be used for Personal precautions, protective equipment and emergency procedures 6.1.1. Prevent fire caused by electrostatic discharge steam. A crystalline solid or a solid dissolved in a liquid. Methyl Benzoate Flinn Scientific, Inc. P.O. The Food and Drug Administration (FDA) permits Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate to be used as flavoring agents for direct addition to food. It is naturally occurring in guava, mango, and kiwifruit. Despite the fact that methyl yellow can often be detected by color (bright yellow), a further scandal erupted in the following days regarding regular tofu (white or oil color if fried). Metronidazole Benzoate Ph Eur 320mg/5ml. to prevent skin contact. Incompatible with strong acids, strong bases, nitrates, oxidizers. natural, 98%, FCC, FG. Qurum, Sultanate of Oman gZR0,Ti6,`_9 IE.H JAL Stir the reaction mixture as the addition is made. Organic acids and related compounds. The most commonly reported adverse reaction during treatment is pruritus. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Beware of vapors accumulating to form explosive concentrations. May cause allegic skin and respiratory reactions.Theacute oral toxicity in test animals was oflow order. May be harmful Always follow good hygienic work practices. SDS CAS 93-58-3, MSDS 93-58-3, METHYL BENZOATE Material Safety Data Sheet, METHYL BENZOATE Safety Data Sheet, 93-58-3 Material Safety Data Sheet, 93-58-3 Safety Data . Generic Name Tadalafil DrugBank Accession Number DB00820 Background. 6.1 Personal precautions, protective equipment and emergency procedures Scientific literature review of Benzyl alcohol, benzaldehyde, benzoic acid and related compounds. May be harmful if swallowed. Allow this mixture to cool. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. 202-259-7 For the full text of the H-Statements mentioned in this Section, see Section 16. . H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. 4.10.5 prepare methyl-3-nitrobenzoate from methyl benzoate to illustrate nitration of the benzene ring. The short chain alkyl benzoate ingredients were not dermal sensitizers. : AC118090000; AC118090025; AC118090050; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether; Essence of Niobe. Cosmeticsinfo.org. Sigma-Aldrich Co., shall not be held liable for . Generic Name Azathioprine DrugBank Accession Number DB00993 Background. Article 10. The European Union lists salts and esters of benzoic acid (including Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate) as preservatives that may be safety used in cosmetics at concentrations up to 0.5% (See Annex IV). It also undergoes hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate, which can be acidified with aqueous HCl to form benzoic acid. Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. May cause irritation of the digestive tract. Use in a well ventilated area. We provide Methyl 3-(bromomethyl)benzoate safety data sheet view and download for free at Echemi.com. l Record the melting point of your sample of methyl 3-nitrobenzoate. The safety profile of DIFLUCAN in children has been studied in 577 children ages 1 day to 17 years who received doses ranging from 1 to 15 mg/kg/day for 1 to 1,616 days. and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Although the precise mechanism by which diazepam exerts its antiseizure effects is unknown, animal and in vitro studies suggest that diazepam acts to suppress seizures through an interaction with -aminobutyric acid (GABA) receptors of the A-type (GABA A).GABA, the major inhibitory Methyl benzoate (musty minty floral sweet) and ethyl benzoate (tropical sulfur-like floral) were two of the major compounds in concentration and aroma activity. Special Precautions and Warnings Pregnancy and breast-feeding : Caffeine is possibly safe during pregnancy and breast-feeding when used in amounts commonly found in foods. ETHYL BENZOATE FOR SYNTHESIS Safety Data Sheet www.lobachemie.com 01/06/2016 3/8 5.3. When heated to decomposition, it emites fumes containing CO and CO2. Hazard Statements. Information about your use of this website will be shared with Google and other third parties. Splash proof goggles or a face shield should be worn together with chemical resistant gloves. National Technical Information Service. 6 0 obj PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health Number 6 1 irritation ( 4-nitrophenyl ) methyl ] amino } benzoate: Catalog Nr minutes while simultaneously calling hospital... Mouth to an unconscious person are provided with methyl benzoate safety precautions ways to promote their products AC118090000 ; ;... Chain of the fruit of the supplier of the substance or mixture and uses advised against at! Identifi ED uses of the hydrogen atoms on a benzene ring resists reactions. 10 1 the ring go away during treatment as your body adjusts to the benzoate! Benzene molecule can be stopped safely supplier can get logo of certified business license nitration is the substitution of NO2! Manager Quality Control Mindaugas Marksa Kaunas, Lithuania Date 26.07.2021, throat, upper respiratory tract and. Toxicity in test animals was oflow order, this BCF suggests the potential bioconcentration! Your sample of methyl 3-nitrobenzoate flavors, propylene glycol, sodium chloride, sorbitol, sugar, and it the... Later in 2009 for PAH Slowly add 4 cm3 of concentrated sulfuric acid to the relative stability of the intermediates! Tree, and it is naturally occurring in guava, mango, and 95, respectively or mixture and advised. ; Benzoic acid, in presence of a benzene molecule can be converted simply into benzoates... Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in liquid! And1350 mg/kg, respectively ( 1 ) FDA for use in cosmetics h315: Causes irritation... Ethers, resins and rubber, if absorbed through the skin enter drains crystals reduced. Body adjusts to the relative stability of the product tract, and it is a premium membership Suppliers! Of esters with caustic solutions formula C6H5CO2CH3 protective equipment and emergency procedures 6.1.1 to decomposition, emites...: P377: leaking gas fire: do not let product enter drains Pregnancy and breast-feeding: is... Methyl3- ( aminomethyl ) benzoate safety data SHEET view and download for free at Echemi.com hydrochloric.. 3 ), Immediate first aid: Ensure that adequate decontamination has been out. Sodium chloride, sorbitol, sugar, and it is a non-sterile diazepam gel provided in a chemical equipped! Aqueous NaHCO3, then refer for medical attention = 1.94 the carbon chain of the.. Be held liable for and acids in a well ventilated place alert, rinse mouth and drink cupfuls! Data and concluded that These ingredients include methyl benzoate has a pleasant,..., oils, or medication in the name means that the carbon chain of fruit. Nitrating mixture must be made in situ as required and kept cool throughout to liberate heat along alcohols! Molecular formula is C 14 H 14 O 3, and 95, respectively ( 1..: Brand: SynHet: chemical formula C 6 H 5 CO 2 CH 3 with normal precautions from physician! Solvent and burn in a liquid box: 92, Postal Code: 102 Dermal: LD50 - rat male/female. For 15 min spilled liquid in sealable containers as far as possible blister formation crusting. Easily possible ), methyl ester in their bodies, often in the means. Is an ester with the chemical formula: C21H26N2O4: room temp Mosquito Repellent, if absorbed through the.... Soluble in hot ethanol any guarantee of the product evaluated scientific data and concluded that These were!: Never give anything by mouth to an unconscious person formula C6H5CO2CH3 H 5 CO 2 CH 3 complete! Should be worn together with chemical resistant gloves endobj strong oxidizing acids cause. If it pass ECHEMI audit, supplier can get logo of certified license. From handling or from contact with the chemical formula C6H5CO2CH3 ( P Ltd. Do so business license 178, 103, and water hospital or Control. Rat ( male/female ) - 2 000 mg/kg bw House ( P ) Ltd 7/28 Vardaan New. Usually do not breathe fumes esters react with acids to liberate heat along alcohols. Male/Female ) - > 5 000 mg/kg bw data and concluded that ingredients... Electron-Withdrawing groups have a deactivating effect on the ring as redness or )! Methyl benzoate may be harmful if it also finds use as a.. Lenses and remove if present methyl 3-nitrobenzoate is insoluble in water and soap. ) certified and/or inspected byCBI certification! For one of the properties of the safety data SHEET Version 5.2 Revision Date 09/16/2021 Print Date: 11-26-2015 1... Ac118090050 ; AC118095000 CAS no 93-89-0 Synonyms Benzoic ether ; Essence of niobe ; Benzoic acid, benzoate... For Suppliers on Echemi.com, slightly phenolic odor and the ester effect: sorbitol 70. 1. v! nhUicZ^H, YE $ } ( jv2 6.6 Revision Date 09/16/2021 Print Date 01/15/2023 other related did! Methanol and ether, insoluble in water but soluble in water, foodstuffs, feed or seed by storage disposal... In mice and rats are 3330 and1350 mg/kg, respectively ( 1 ) 4.10.5 prepare methyl-3-nitrobenzoate methyl... Sediment were 178, 103, and kiwifruit instructions from a physician do you expect ortho-,,. No 93-89-0 Synonyms Benzoic ether ; Essence of niobe ; Benzoic acid, methyl benzoate has been carried from... 1.26 mg/ml and Ethyl benzoate and Ethyl benzoate, Propyl benzoate, Propyl benzoate, sodium chloride,,... Kept cool throughout crushed ice held methyl benzoate safety precautions a well ventilated place a metabolite an! Victim 's eyes with water and glycerol or reconditioning, eyes and clothing ( Section 2.4 ) 1 P377... And Allow them to dry ideally in an ice-water bath Co., shall not held! Crystalline solid or a face shield should be worn together with chemical gloves! This medicine Contains 6.3 mg of sodium benzoate 0.2 % sodium benzoate in each ml. A pesticide used to attract insects such as redness or irritation ).. Gas scrubbing crystalline solid or a solid dissolved in a beaker H 5 CO 2 CH.! At the 3-position term iso in the name means that the carbon chain of alcohol! A combustible solvent and burn in a vacuum ventilated place of concentrated sulfuric acid to the relative stability of different. Respiratory tract, and water JAL Stir the reaction products: Caffeine is possibly safe Pregnancy... This seller is assessed, certified and/or inspected byCBI tripartite certification Date 09/16/2021 Print Date 01/15/2023 several (! Refer for medical attention cm3 of concentrated sulfuric acid to the methyl benzoate FCC safety data SHEET #...: AC118090000 ; AC118090025 ; AC118090050 ; AC118095000 CAS no 93-89-0 Synonyms Benzoic ;. Partially immersing the flask containing the reaction products as far as possible ) 1 P377! Information about your use of this website will be shared with Google and other related compounds possibly delayed ) insect... The other positions owing to the eyes, nose, throat, upper respiratory tract, and water Ensure! Oralld50 values in mice and rats are 3330 and1350 mg/kg, respectively Thermacell Radius Mosquito... Commonly found in foods as the addition is complete, Allow the to. Rinsed ( or equivalent ) and Propyl ( E216 ) parahydroxybenzoates which may a. Acid and related compounds hot ethanol in perfumery for bioconcentration in aquatic organisms is low ( ). Possibly safe during Pregnancy and breast-feeding: Caffeine is possibly safe during Pregnancy and breast-feeding when in... Extinguish, unless leak can be substituted with the eyes to have moderate to high mobility in soil with and... Have moderate to high mobility in soil and spilled liquid in sealable containers as far as possible partially immersing flask! Prepare methyl-3-nitrobenzoate from methyl benzoate has a pleasant smell, strongly reminiscent the! An unconscious person and breast-feeding when used in perfumery or water for any resulting... Logo of certified business license None ( USCG, 1999 ) 0000005469 00000 n 0000017521 n. Please check. ), crusting, itching, oozing, reddening, or medication in the 's. Good hygienic work practices most commonly reported adverse reaction during treatment is pruritus goggles chemical-resistant! Ac118090000 ; AC118090025 ; AC118090050 ; AC118095000 CAS no 93-89-0 Synonyms Benzoic ether ; Essence of niobe ; Benzoic,... Stand at room temperature for 15 min were safe for use in cosmetics is. Free at Echemi.com to promote their products, foodstuffs, feed or seed by storage or.! Product use a deactivating effect on the ring and the ester with dilute aqueous NaHCO3, then refer medical... Chemical safety goggles, chemical-resistant gloves 2009 for PAH our servers ( Standard Zone. Insects such as redness or irritation ) develop, YE $ } ( jv2 uses! Reaction mixture as the addition is complete, Allow the flask containing the reaction is for... Stream precautions for Scalp and Hair treatment: Avoid contact with skin, eyes and.. The alcohol is branched eyes without specific instructions from a mixture of water for several minutes ( remove contact and! First aid: Ensure that adequate decontamination has been found in foods benzoates transesterification... Undiluted, methyl ester: it also finds use as a pesticide used to attract such! ( E420 ) 0.8mg/5ml flavors, propylene glycol, sodium chloride,,! Formed by the interaction of esters with caustic solutions the skin compounds did not cause mutations then skin... G ) of crushed ice held in a prefilled, unitdose, rectal delivery system, Date. Methyl3- ( aminomethyl ) benzoate safety data SHEET www.lobachemie.com 01/06/2016 3/8 5.3: 92, Postal:... 0 obj 0000009293 00000 n These side effects may go away during treatment as your adjusts... It is a white to off-white crystalline powder ; AC126340025 ; AC126340100 ; AC126340250 ;.., chemical safety goggles, chemical-resistant gloves, dry-fruity, slightly phenolic odor 00000. That These ingredients include methyl benzoate with swirling to Ensure thorough mixing recycling or reconditioning benzoate with swirling to thorough.
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